Cathode Reaction of Titanium Chloride in Molten LiCl-KCl Eutectic Mixture
نویسندگان
چکیده
منابع مشابه
EXCESS HEAT IN MOLTEN SALTS OF (LiCl − KCl) + (LiD + LiF) AT THE TITANIUM ANODE DURING ELECTROLYSIS
The electrochemical cell and a technique for precision calorimetric measurements has been developed. Experiments with molten salts containing lithium deuteride were carried out. Calorimetric measurements made on the titanium anode during experiments. Measurements were made in an inert atmosphere of helium and in an atmosphere of deuterium at various density of an electrolysis current. Excess he...
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The dependence of indium electro de potential vs. log. concentration of indium (III) is linear and the slopes determined are comparable with the slopes calculated from the Nernst equation, assuming n = 3. The potential of In/ln(III) has been determined to be 0.805 ± 0.003 V with respect to Pt/PtC12 (1 M). At 693 K the free energy of formation of the indium(III) chloride in a 1 M solution is -32...
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Molybdenum(VI) oxide reacts with molten LiC1-KCI eutectie at 450 ~ to form MOO2C12, which probably is present as an anion MoO2Cl4 =, and pyromolybdate, Mo207 =. Both of these species are electrochemically reduced to MOO2, which can be reoxidized to MoO2CI2 by current reversal. A second reduction step, observed whether MoO3 or Mo2072is added to the melt, can be attributed to the reduction of MoO...
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Titanium-silicon alloys have been electrochemically extracted from the multi-component titanium compounds in molten calcium chloride electrolyte. Sintered pressed pellets of titanium-bearing compounds served as the cathode, and the electrochemical experiments were systematically carried out at 900 °C, 3.1 V and 1000 °C, 3.8 V using a graphite-based anode and an improved inert-oxygen-ion-conduct...
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ژورنال
عنوان ژورنال: Denki Kagaku oyobi Kogyo Butsuri Kagaku
سال: 1974
ISSN: 0366-9297,2434-2556
DOI: 10.5796/kogyobutsurikagaku.42.175